avatarDr Joel Yong, PhD

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cheap, and there’s a whole ton of feedstock for producing all that corn and soybean oil that we see in the supermarkets today. And I’m not even listing the other plant based oils that we can find in those supermarkets.</p><p id="99e0">To eliminate all that stock, can we market it so that unsaturated vegetable oil is “healthier” than saturated animal fat? <b><i>It’s already been done. It still is the prevailing opinion among many people today.</i></b></p><p id="bc3c">The problem is that unsaturated fats are just too darned unstable. Polyunsaturated fats contain multiple carbon-carbon double bonds (C=C), all of which are particularly <b><i>susceptible to oxidation</i></b> by atmospheric oxygen:</p><div id="3665" class="link-block"> <a href="https://readmedium.com/whats-so-bad-about-unsaturated-fatty-acid-oxidation-9f467d6af8ef"> <div> <div> <h2>What’s So Bad About Unsaturated Fatty Acid Oxidation?</h2> <div><h3>Why would this oxidation be so damaging to us?</h3></div> <div><p>medium.com</p></div> </div> <div> <div style="background-image: url(https://miro.readmedium.com/v2/resize:fit:320/0*t1wfD0t3eS22btqa)"></div> </div> </div> </a> </div><p id="860f">Hence they can go rancid very easily. They undergo an oxidation process known as <a href="https://pubmed.ncbi.nlm.nih.gov/20964436/">lipid peroxidation</a>, which creates more toxic by-products such as <a href="https://www.nature.com/articles/cddis2016275">aldehydes</a>. We’ve seen what too many aldehydes in our body can do already:</p><div id="bf1f" class="link-block"> <a href="https://readmedium.com/one-unifying-chemical-reaction-to-explain-why-we-shouldnt-feed-ourselves-with-all-the-wrong-foods-706842d0d96d"> <div> <div> <h2>One Unifying Chemical Reaction To Explain Why We Shouldn’t Feed Ourselves With All The Wrong Foods.</h2> <div><h3>It’s just one aldehyde, c’mon. What can it really do?</h3></div> <div><p>medium.com</p></div> </div> <div> <div style="background-image: url(https://miro.readmedium.com/v2/resize:fit:320/0*7K5lHJDtjVKVaqeS)"></div> </div> </div> </a> </div><p id="fcfe">To protect these unsaturated fats and turn them into a more solidified mass, as it is in the case of margarine, one option is to <a href="https://www.fsai.ie/faq/trans_fatty_acids.html"><b><i>hydrogenate</i></b></a><b><i> </i></b>those C=C double bonds, which we can do by reacting it with hydrogen in the presence of a <a href="https://chem.libretexts.org/Bookshelves/Organic_Chemistry/Supplemental_Modules_(Organic_Chemistry)/Alkenes/Reactivity_of_Alkenes/Stereoselectivity_in_Addition_Reactions_to_Double_Bonds/Hydrogenation_of_Alkenes">palladium, platinum or nickel</a> catalyst.</p><p id="6336">Hence we can come up with margarine products that contain partially hydrogenated vegetable oils.</p><p id="ab04"><b><i>And people tend to think that it’s “healthier” than butter because it’s not saturated animal

Options

fat, according to the prevailing narrative.</i></b></p><p id="5104">The problem with the hydrogenation process is that it has to occur at <a href="https://www.sciencedirect.com/science/article/pii/B9780128094372000101">high temperature and pressure</a>. Now, if the reaction environment were not carefully controlled to eliminate <b><i>all </i></b>traces of atmospheric oxygen, that high temperature can easily cause oxygen to react with the C=C double bonds to form the lipid peroxides that can be toxic and carcinogenic to the human body:</p><div id="993e" class="link-block"> <a href="https://readmedium.com/how-lipid-peroxidation-affects-the-omega-3-fatty-acid-5c96a1fd411b"> <div> <div> <h2>How Lipid Peroxidation Affects The Omega-3 Fatty Acid</h2> <div><h3>What does lipid peroxidation do to the omega-3 fatty acid molecule?</h3></div> <div><p>medium.com</p></div> </div> <div> <div style="background-image: url(https://miro.readmedium.com/v2/resize:fit:320/0*tYNZHKhdI-n7_Kol)"></div> </div> </div> </a> </div><p id="30e6">Which is definitely something that we would want to avoid.</p><p id="6ed3">Whether we’re considering the partial or the complete hydrogenation reactions, we have to remember that the chemical reaction requires high temperatures and pressures to proceed.</p><p id="fa6d">This means that <b><i>regardless </i></b>of how complete the hydrogenation reaction is, we will still be seeing the <b><i>side reactions</i></b> affecting some of the C=C double bonds in those unsaturated fats. The more C=C double bonds there are, the greater there is a chance of the C=C double bond oxidation reactions occurring.</p><p id="7fca">Therefore it isn’t to our best interest to be consuming foods made with hydrogenated fats at all. The <b><i>risk</i></b> of ingesting all those lipid peroxides would be much higher!</p><p id="5dab"><i>Joel Yong, Ph.D., is a biochemical engineer/scientist, an educator and a writer. He has authored 5 ebooks (available on <a href="https://www.amazon.com/Dr-Joel-Yong/e/B08LQ7K1KD">Amazon.com</a> in Kindle format) and co-authored 6 journal articles in internationally peer-reviewed scientific journals. His main focus is on crafting strategies to support optimal biochemical functions in the human body at <a href="https://thethinkingscientist.substack.com/">https://thethinkingscientist.substack.com</a>.</i></p><div id="f63a" class="link-block"> <a href="https://thethinkingscientist.medium.com/membership"> <div> <div> <h2>Join Medium with my referral link - Dr Joel Yong, PhD</h2> <div><h3>Read every story from Dr Joel Yong, PhD (and thousands of other writers on Medium). Your membership fee directly…</h3></div> <div><p>thethinkingscientist.medium.com</p></div> </div> <div> <div style="background-image: url(https://miro.readmedium.com/v2/resize:fit:320/0*Cd046vxxy3Pev1j4)"></div> </div> </div> </a> </div></article></body>

Why Is Hydrogenated Vegetable Oil Something That We Don’t Want To Be Consuming In Excess?

What does it mean when a product contains hydrogenated vegetable oils?

Photo by Sincerely Media on Unsplash

We’ve had butter around for so long. Some say it was discovered in 8000 BC in ancient Africa, when a sheepskin container of milk was jostled around in land travel, resulting in the development of a curdled mixture that became known as butter.

Of course, the “problem” that some people say exists with butter is that it consists of saturated fat, and the overconsumption of saturated fat is arguably related to cholesterol and heart disease issues.

(To be honest, I don’t think it really is. Link to heart disease article below)

But when the prevailing narrative problem statement is that saturated animal fats can cause heart disease, then it does make sense to develop a “solution” that relies on unsaturated vegetable oils, isn’t it?

Why would unsaturated vegetable oils be marketed, though?

It’s a political matter that is linked to the heavy subsidies of crops such as corn and soybeans — and of course, corn and soybeans are significant providers of vegetable oil. We can see gallons and gallons of them in the supermarkets at any time.

They’re subsidised and cheap, and there’s a whole ton of feedstock for producing all that corn and soybean oil that we see in the supermarkets today. And I’m not even listing the other plant based oils that we can find in those supermarkets.

To eliminate all that stock, can we market it so that unsaturated vegetable oil is “healthier” than saturated animal fat? It’s already been done. It still is the prevailing opinion among many people today.

The problem is that unsaturated fats are just too darned unstable. Polyunsaturated fats contain multiple carbon-carbon double bonds (C=C), all of which are particularly susceptible to oxidation by atmospheric oxygen:

Hence they can go rancid very easily. They undergo an oxidation process known as lipid peroxidation, which creates more toxic by-products such as aldehydes. We’ve seen what too many aldehydes in our body can do already:

To protect these unsaturated fats and turn them into a more solidified mass, as it is in the case of margarine, one option is to hydrogenate those C=C double bonds, which we can do by reacting it with hydrogen in the presence of a palladium, platinum or nickel catalyst.

Hence we can come up with margarine products that contain partially hydrogenated vegetable oils.

And people tend to think that it’s “healthier” than butter because it’s not saturated animal fat, according to the prevailing narrative.

The problem with the hydrogenation process is that it has to occur at high temperature and pressure. Now, if the reaction environment were not carefully controlled to eliminate all traces of atmospheric oxygen, that high temperature can easily cause oxygen to react with the C=C double bonds to form the lipid peroxides that can be toxic and carcinogenic to the human body:

Which is definitely something that we would want to avoid.

Whether we’re considering the partial or the complete hydrogenation reactions, we have to remember that the chemical reaction requires high temperatures and pressures to proceed.

This means that regardless of how complete the hydrogenation reaction is, we will still be seeing the side reactions affecting some of the C=C double bonds in those unsaturated fats. The more C=C double bonds there are, the greater there is a chance of the C=C double bond oxidation reactions occurring.

Therefore it isn’t to our best interest to be consuming foods made with hydrogenated fats at all. The risk of ingesting all those lipid peroxides would be much higher!

Joel Yong, Ph.D., is a biochemical engineer/scientist, an educator and a writer. He has authored 5 ebooks (available on Amazon.com in Kindle format) and co-authored 6 journal articles in internationally peer-reviewed scientific journals. His main focus is on crafting strategies to support optimal biochemical functions in the human body at https://thethinkingscientist.substack.com.

Health
Science
Food
Nutrition
Lifestyle
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