avatarLucianoSphere (Luciano Abriata, PhD)

Free AI web copilot to create summaries, insights and extended knowledge, download it at here

2668

Abstract

end solutions were around 0.01 M which means pH around 2 and 12. The solutions were properly neutralized before disposal. Do not do this at home if you don’t know what you are doing -just stay with the 3 central pH values achieved with household chemicals as in the previous figure. Photo by author Luciano Abriata.</figcaption></figure><p id="74dd">Notice that at the more extreme pH values, the acidic form becomes less purple and more pink/red, while the basic form shifts from blue to green.</p><p id="d2e9"><b>To improve colors…</b></p><p id="ca0f">I noticed the solutions were a bit too concentrated, so I added similar amounts of water to all 5 glasses and took photos. The different colors are clearer in this way. These were my best results:</p><figure id="4756"><img src="https://cdn-images-1.readmedium.com/v2/resize:fit:800/1*3djG29fkTWED3CyuCq-iVA.png"><figcaption>View from top after having added more water to the solutions of the previous photo. Photo by author.</figcaption></figure><figure id="30d3"><img src="https://cdn-images-1.readmedium.com/v2/resize:fit:800/1*mX4tbvn_e8O4tybgLInMOw.png"><figcaption>Another view. Photo by author Luciano Abriata.</figcaption></figure><figure id="505c"><img src="https://cdn-images-1.readmedium.com/v2/resize:fit:800/1*IVkvlczDYIE9je9rJyXnkg.png"><figcaption>Side view of the final solutions. Photo by author Luciano Abriata.</figcaption></figure><p id="8234"><b>Why does this happen?</b></p><p id="3c9f">The solution behaves as a pH indicator, thanks to a series of molecules called anthocyanins that exchange some of their H atoms: at low pH (acidic medium) the H atoms “attach” to the molecule, and at high pH (basic medium) they “detach” from the molecule. The forms with and without H atoms have different light absorption properties. There are 4 of these forms: one that is red (at very low pH), another is violet (somewhat acidic pH), another is blue (neutral to slightly basic pH), and the last is yellow (at very high pH). With our solutions we do not reach a very high pH, so we see a mixture of blue and yellow which looks like green.</p><figure id="8bd9"><img src="https://cdn-images-1.readmedium.com/v2/resize:fit:800/1*EDIbe1nNguMnNldd7knH6g.png"><figcaption>An anthocyanin molecule shot with the moleculARweb site for chemistry in augmented reality (story to come some day!). Screenshot by author Luciano Abriata.</figcaption></figure><p id="3bb9"><b>Storing the solution for later use</b></p><p id="6470">The solution works best if you use it right after preparing it, but it can last quite some months in the fridge. Three months is the longest I’ve tried so far, and it was ok. For longer-ter

Options

m storage, you may try freezing cubes of the solution, and thawing them one by one when you want to play.</p><p id="66d8"><b>More color fun with chemistry and cabbage + further reads</b></p><p id="f25f">If you have access to stronger acids or bases and you know what you are doing, you can produce more extreme pHs. At the low pH extreme not much more will happen (just the red becomes redder), but at high pH you will see another transition from green to yellow. You can see the full scale in this post at compoundchem.com:</p><div id="97a8" class="link-block"> <a href="https://www.compoundchem.com/2017/05/18/red-cabbage/"> <div> <div> <h2>Making a Red Cabbage pH Indicator: The Method and the Chemistry</h2> <div><h3>We all know examples of everyday substances that can be classified as acids or alkalis: lemon juice is acidic, bleach…</h3></div> <div><p>www.compoundchem.com</p></div> </div> <div> <div style="background-image: url(https://miro.readmedium.com/v2/resize:fit:320/0*tZro-FwEosWhkL4j)"></div> </div> </div> </a> </div><p id="d143">A related, very interesting post at compoundchem.com deals with the change in colors of the Christmas plant poinsettia (<i>Euphorbia pulcherrima</i>):</p><div id="84c8" class="link-block"> <a href="https://www.compoundchem.com/2014/12/02/poinsettia/"> <div> <div> <h2>The Chemistry of Poinsettia Plants</h2> <div><h3>Following on from the start of the Chemistry Advent Calendar yesterday, here's another festive post, this time looking…</h3></div> <div><p>www.compoundchem.com</p></div> </div> <div> <div style="background-image: url(https://miro.readmedium.com/v2/resize:fit:320/0*Bku0kbZk5kijbNGu)"></div> </div> </div> </a> </div><p id="165d"><b>Go have fun!</b></p><p id="0fb0"><i>I am a nature, science, technology, programming, and DIY enthusiast. Biotechnologist and chemist, in the wet lab and in computers. I write about everything that lies within my broad sphere of interests. Check out my <a href="https://lucianosphere.medium.com/lists">lists</a> for more stories. <a href="https://lucianosphere.medium.com/membership">Become a Medium member</a> to access all stories by me and other writers, and <a href="https://lucianosphere.medium.com/subscribe">subscribe to get my new stories</a> by email (original affiliate links of the platform).</i></p></article></body>

Red cabbage solutions of increasing pH from left to right. Photo by author Luciano Abriata.

Fun with colors with at-home chemistry

The color of cabbage extract is very sensitive to pH, so you can get a very rich palette with simple household chemicals.

Step 1: Get and chop some red cabbage. For this example, I chopped a quarter of a cabbage, but I’m sure less works too:

Step 1: chopping a piece of cabbage in very small pieces. Photo by author Luciano Abriata.

Step 2: Add water and boil. Add just enough water to cover the chopped leaves and boil for 10 minutes or so. Then filter to keep only the solution, which will most likely be dark purple like here (the exact color may vary, as it depends on pH !)

Boil the chopped cabbage with some water, for around 10 minutes. Photo by author Luciano Abriata.

Step 3: Fun with colors using safe household chemicals. Dispense the liquid in flasks, tubes, or just normal glasses; and add various acids or bases. Here in the center you see the solution as prepared, and then with vinegar (acetic acid, which is acidic) on the left and with baking soda (sodium bicarbonate, which is basic) on the right:

Center: cabbage extract as prepared has near neutral pH, producing a purple color. Left: acetic acid drops the pH, turning the solution more red. Right: bicarbonate increases the pH, turning the solution more blue. Photo by author Luciano Abriata.

I added here two more glasses with solution, plus: hydrochloric acid (HCl) to the leftmost, which results in a solution more acidic (lower pH) than the one containing vinegar; and sodium hydroxyde (NaOH) to the rightmost, which gets more basic (higher pH) than the solution containing sodium bicarbonate:

Getting pH extremes with a non-household acid (HCl) and base (NaOH). Each was added from a 1 M stock. Given the dilutions, the end solutions were around 0.01 M which means pH around 2 and 12. The solutions were properly neutralized before disposal. Do not do this at home if you don’t know what you are doing -just stay with the 3 central pH values achieved with household chemicals as in the previous figure. Photo by author Luciano Abriata.

Notice that at the more extreme pH values, the acidic form becomes less purple and more pink/red, while the basic form shifts from blue to green.

To improve colors…

I noticed the solutions were a bit too concentrated, so I added similar amounts of water to all 5 glasses and took photos. The different colors are clearer in this way. These were my best results:

View from top after having added more water to the solutions of the previous photo. Photo by author.
Another view. Photo by author Luciano Abriata.
Side view of the final solutions. Photo by author Luciano Abriata.

Why does this happen?

The solution behaves as a pH indicator, thanks to a series of molecules called anthocyanins that exchange some of their H atoms: at low pH (acidic medium) the H atoms “attach” to the molecule, and at high pH (basic medium) they “detach” from the molecule. The forms with and without H atoms have different light absorption properties. There are 4 of these forms: one that is red (at very low pH), another is violet (somewhat acidic pH), another is blue (neutral to slightly basic pH), and the last is yellow (at very high pH). With our solutions we do not reach a very high pH, so we see a mixture of blue and yellow which looks like green.

An anthocyanin molecule shot with the moleculARweb site for chemistry in augmented reality (story to come some day!). Screenshot by author Luciano Abriata.

Storing the solution for later use

The solution works best if you use it right after preparing it, but it can last quite some months in the fridge. Three months is the longest I’ve tried so far, and it was ok. For longer-term storage, you may try freezing cubes of the solution, and thawing them one by one when you want to play.

More color fun with chemistry and cabbage + further reads

If you have access to stronger acids or bases and you know what you are doing, you can produce more extreme pHs. At the low pH extreme not much more will happen (just the red becomes redder), but at high pH you will see another transition from green to yellow. You can see the full scale in this post at compoundchem.com:

A related, very interesting post at compoundchem.com deals with the change in colors of the Christmas plant poinsettia (Euphorbia pulcherrima):

Go have fun!

I am a nature, science, technology, programming, and DIY enthusiast. Biotechnologist and chemist, in the wet lab and in computers. I write about everything that lies within my broad sphere of interests. Check out my lists for more stories. Become a Medium member to access all stories by me and other writers, and subscribe to get my new stories by email (original affiliate links of the platform).

Chemistry
Science
Education
Photography
Art
Recommended from ReadMedium